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Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C–H Bonds
Several classes of enantioselective silylations of C–H bonds have been reported recently, but little mechanistic data on these processes are available. We report mechanistic studies on the rhodium-catalyzed, enantioselective silylation of aryl C–H bonds. A rhodium silyl dihydride and a rhodium norbo...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5810545/ https://ncbi.nlm.nih.gov/pubmed/28278372 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b00737 |
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