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Ir-Catalyzed Enantioselective, Intramolecular Silylation of Methyl C–H Bonds
We report highly enantioselective intra-molecular, silylations of unactivated, primary C(sp(3))–H bonds. The reactions form dihydrobenzosiloles in high yields with excellent enantioselectivities by functionalization of enantiotopic methyl groups under mild conditions. The reaction is catalyzed by an...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5809130/ https://ncbi.nlm.nih.gov/pubmed/28820264 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b06679 |
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