Enantioselective Synthesis of N,S-Acetals by an Oxidative Pummerer Type Transformation Using Anionic Phase-Transfer Catalysis

We report the first enantioselective oxidative Pummerer-type transformation using anionic phase-transfer catalysis, resulting in the formation of enantioenriched sulfur bearing heterocycles. This reaction includes the direct oxidation of sulfides to the thionium intermediate, followed by an asymmetr...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Biswas, Souvagya, Kubota, Koji, Orlandi, Manuel, Turberg, Mathias, Miles, Dillon H., Sigman, Matthew S., Dean Toste, F.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2017
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5767526/
https://ncbi.nlm.nih.gov/pubmed/29171138
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201711277
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