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A combination of directing groups and chiral anion phase-transfer catalysis for enantioselective fluorination of alkenes
We report a catalytic enantioselective electrophilic fluorination of alkenes to form tertiary and quaternary C(sp3)-F bonds and generate β-amino- and β-aryl-allylic fluorides. The reaction takes advantage of the ability of chiral phosphate anions to serve as solid–liquid phase transfer catalysts and...
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| 主要な著者: | , , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
National Academy of Sciences
2013
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3752255/ https://ncbi.nlm.nih.gov/pubmed/23922394 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1304346110 |
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