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Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis
A palladium-catalyzed three-component coupling of α-olefins, aryldiazonium salts, and bis-(pinacolato)diboron affords direct access to chiral benzylic boronic esters. This process is rendered highly enantioselective using an unprecedented example of cooperative chiral anion phase transfer and transi...
Tallennettuna:
| Julkaisussa: | J Am Chem Soc |
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| Päätekijät: | , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2015
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4564013/ https://ncbi.nlm.nih.gov/pubmed/25723255 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00344 |
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