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Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase-Transfer
The enantioselective 1,1-diarylation of terminal alkenes is reported herein enabled by the combination of palladium catalysis with a chiral anion phase-transfer strategy. The reaction of substituted benzyl acrylates with aryldiazonium salts and arylboronic acids gave the corresponding 3,3-diaryl pro...
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| Publicado no: | J Am Chem Soc |
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| Principais autores: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5217716/ https://ncbi.nlm.nih.gov/pubmed/27960315 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11367 |
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