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Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase-Transfer

The enantioselective 1,1-diarylation of terminal alkenes is reported herein enabled by the combination of palladium catalysis with a chiral anion phase-transfer strategy. The reaction of substituted benzyl acrylates with aryldiazonium salts and arylboronic acids gave the corresponding 3,3-diaryl pro...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Yamamoto, Eiji, Hilton, Margaret J., Orlandi, Manuel, Saini, Vaneet, Toste, F. Dean, Sigman, Matthew S.
Format: Artigo
Sprog:Inglês
Udgivet: 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5217716/
https://ncbi.nlm.nih.gov/pubmed/27960315
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11367
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