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Sulfamate Esters Guide Selective Radical-Mediated Chlorination of Aliphatic C–H Bonds
Masked alcohols are particularly appealing as directing groups because of the ubiquity of hydroxyl groups in organic small molecules. Herein, we disclose a general strategy for aliphatic γ-C(sp(3))–H functionalization guided by a masked alcohol. Specifically, we determine that sulfamate ester-derive...
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| Gepubliceerd in: | Angew Chem Int Ed Engl |
|---|---|
| Hoofdauteurs: | , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2017
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5745255/ https://ncbi.nlm.nih.gov/pubmed/29096044 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201710322 |
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