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Sulfamides direct radical-mediated chlorination of aliphatic C–H bonds
Given the prevalence of aliphatic amines in bioactive small molecules, amine derivatives are opportune as directing groups. Herein, sulfamides serve as amine surrogates to guide intermolecular chlorine-transfer at γ-C(sp(3)) centers. This unusual position-selectivity arises because accessed sulfamid...
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| 出版年: | Chem Sci |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
The Royal Society of Chemistry
2019
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8132995/ https://ncbi.nlm.nih.gov/pubmed/34040715 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03428e |
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