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Sulfamides direct radical-mediated chlorination of aliphatic C–H bonds

Given the prevalence of aliphatic amines in bioactive small molecules, amine derivatives are opportune as directing groups. Herein, sulfamides serve as amine surrogates to guide intermolecular chlorine-transfer at γ-C(sp(3)) centers. This unusual position-selectivity arises because accessed sulfamid...

詳細記述

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書誌詳細
出版年:Chem Sci
主要な著者: Short, Melanie A., Shehata, Mina F., Sanders, Matthew A., Roizen, Jennifer L.
フォーマット: Artigo
言語:Inglês
出版事項: The Royal Society of Chemistry 2019
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC8132995/
https://ncbi.nlm.nih.gov/pubmed/34040715
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03428e
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