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Sulfamides direct radical-mediated chlorination of aliphatic C–H bonds
Given the prevalence of aliphatic amines in bioactive small molecules, amine derivatives are opportune as directing groups. Herein, sulfamides serve as amine surrogates to guide intermolecular chlorine-transfer at γ-C(sp(3)) centers. This unusual position-selectivity arises because accessed sulfamid...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
The Royal Society of Chemistry
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8132995/ https://ncbi.nlm.nih.gov/pubmed/34040715 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03428e |
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