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Catalytic asymmetric synthesis of a nitrogen heterocycle through stereocontrolled direct photoreaction from electronically excited state

The reactivity of photoexcited molecules has been extensively studied for decades but until today direct bond-forming reactions of such excited states in a catalytic and asymmetric fashion are restricted to the synthesis of cyclobutanes via [2 + 2] photocycloadditions. Herein, we demonstrate a previ...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Huang, Xiaoqiang, Li, Xinyao, Xie, Xiulan, Harms, Klaus, Riedel, Radostan, Meggers, Eric
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5740077/
https://ncbi.nlm.nih.gov/pubmed/29269853
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-017-02148-1
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