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Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical–radical coupling
A new mechanistic approach for the catalytic, enantioselective conjugate addition of nitrogen-based nucleophiles to acceptor-substituted alkenes is reported, which is based on a visible light induced and phosphate base promoted transfer of a single electron from a nitrogen nucleophile to a catalyst-...
Shranjeno v:
| izdano v: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2017
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5621506/ https://ncbi.nlm.nih.gov/pubmed/28989615 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02031g |
| Oznake: |
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