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Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical–radical coupling

A new mechanistic approach for the catalytic, enantioselective conjugate addition of nitrogen-based nucleophiles to acceptor-substituted alkenes is reported, which is based on a visible light induced and phosphate base promoted transfer of a single electron from a nitrogen nucleophile to a catalyst-...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Zhou, Zijun, Li, Yanjun, Han, Bowen, Gong, Lei, Meggers, Eric
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2017
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5621506/
https://ncbi.nlm.nih.gov/pubmed/28989615
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02031g
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