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Catalytic Olefin Hydroamidation Enabled by Proton-Coupled Electron Transfer
[Image: see text] Here we report a ternary catalyst system for the intramolecular hydroamidation of unactivated olefins using simple N-aryl amide derivatives. Amide activation in these reactions occurs via concerted proton-coupled electron transfer (PCET) mediated by an excited state iridium complex...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | J Am Chem Soc |
|---|---|
| Prif Awduron: | , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
American Chemical
Society
2015
|
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4629195/ https://ncbi.nlm.nih.gov/pubmed/26439818 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b09671 |
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