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Catalytic Ring Expansions of Cyclic Alcohols Enabled by Proton-Coupled Electron Transfer
We report here a catalytic method for the modular ring expansion of cyclic aliphatic alcohols. In this work, proton-coupled electron transfer (PCET) activation of an allylic alcohol substrate affords an alkoxy radical intermediate that undergoes subsequent C–C bond cleavage to furnish an enone and a...
Enregistré dans:
| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7219538/ https://ncbi.nlm.nih.gov/pubmed/31117664 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b03973 |
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