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Catalytic Hydroetherification of Unactivated Alkenes Enabled by Proton-Coupled Electron Transfer

We report a catalytic, light-driven protocol for the intramolecular hydroetherification of unactivated alkenols to furnish cyclic ether products. These reactions occur under visible light irradiation in the presence of an Ir(III)-based photoredox catalyst, a Brønsted base catalyst, and a hydrogen at...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Tsui, Elaine, Metrano, Anthony J., Tsuchiya, Yuto, Knowles, Robert R.
Format: Artigo
Langue:Inglês
Publié: 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7451027/
https://ncbi.nlm.nih.gov/pubmed/32227658
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202003959
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