Synthesis of Diarylated 4-Pyridylmethyl Ethers via Palladium-Catalyzed Cross-Coupling Reactions

The direct arylation of weakly acidic sp(3)–hybridized C–H bonds via deprotonated cross–coupling processes (DCCP) is a challenge. Herein, a Pd(NIXANTPHOS)-based catalyst for the mono arylation of 4-pyridylmethyl 2-aryl ethers to generate diarylated 4-pyridyl methyl ethers is introduced. Furthermore,...

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Publicado en:Adv Synth Catal
Autores principales: Ablajan, Keyume, Panetti, Grace B., Yang, Xiaodong, Kim, Byeong-Seon, Walsh, Patrick J.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2017
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5722243/
https://ncbi.nlm.nih.gov/pubmed/29230153
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201700380
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