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Gold(III) Alkyne Complexes: Bonding and Reaction Pathways

The synthesis and characterization of hitherto hypothetical Au(III) π‐alkyne complexes is reported. Bonding and stability depend strongly on the trans effect and steric factors. Bonding characteristics shed light on the reasons for the very different stabilities between the classical alkyne complexe...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Rocchigiani, Luca, Fernandez‐Cestau, Julio, Agonigi, Gabriele, Chambrier, Isabelle, Budzelaar, Peter H. M., Bochmann, Manfred
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5698712/
https://ncbi.nlm.nih.gov/pubmed/28892244
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708640
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