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Gold(III) Alkyne Complexes: Bonding and Reaction Pathways

The synthesis and characterization of hitherto hypothetical Au(III) π‐alkyne complexes is reported. Bonding and stability depend strongly on the trans effect and steric factors. Bonding characteristics shed light on the reasons for the very different stabilities between the classical alkyne complexe...

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Bibliografische gegevens
Gepubliceerd in:Angew Chem Int Ed Engl
Hoofdauteurs: Rocchigiani, Luca, Fernandez‐Cestau, Julio, Agonigi, Gabriele, Chambrier, Isabelle, Budzelaar, Peter H. M., Bochmann, Manfred
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: John Wiley and Sons Inc. 2017
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5698712/
https://ncbi.nlm.nih.gov/pubmed/28892244
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708640
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