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Gold(III)-CO and gold(III)-CO(2) complexes and their role in the water-gas shift reaction

The water-gas shift (WGS) reaction is an important process for the generation of hydrogen. Heterogeneous gold catalysts exhibit good WGS activity, but the nature of the active site, the oxidation state, and competing reaction mechanisms are very much matters of debate. Homogeneous gold WGS systems t...

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Detalhes bibliográficos
Publicado no:Sci Adv
Main Authors: Roşca, Dragoş-Adrian, Fernandez-Cestau, Julio, Morris, James, Wright, Joseph A., Bochmann, Manfred
Formato: Artigo
Idioma:Inglês
Publicado em: American Association for the Advancement of Science 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4646827/
https://ncbi.nlm.nih.gov/pubmed/26601313
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/sciadv.1500761
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