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Formation of Gold(III) Alkyls from Gold Alkoxide Complexes
[Image: see text] The gold(III) methoxide complex (C(∧)N(∧)C)AuOMe (1) reacts with tris(p-tolyl)phosphine in benzene at room temperature under O abstraction to give the methylgold product (C(∧)N(∧)C)AuMe (2) together with O=P(p-tol)(3) ((C(∧)N(∧)C) = [2,6-(C(6)H(3)(t)Bu-4)(2)pyridine](2–)). Calculat...
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| Publicado no: | Organometallics |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2017
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5388904/ https://ncbi.nlm.nih.gov/pubmed/28413238 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.7b00077 |
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