Gold(III) Alkyne Complexes: Bonding and Reaction Pathways

The synthesis and characterization of hitherto hypothetical Au(III) π‐alkyne complexes is reported. Bonding and stability depend strongly on the trans effect and steric factors. Bonding characteristics shed light on the reasons for the very different stabilities between the classical alkyne complexe...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Angew Chem Int Ed Engl
Prif Awduron: Rocchigiani, Luca, Fernandez‐Cestau, Julio, Agonigi, Gabriele, Chambrier, Isabelle, Budzelaar, Peter H. M., Bochmann, Manfred
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: John Wiley and Sons Inc. 2017
Pynciau:
Communications
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5698712/
https://ncbi.nlm.nih.gov/pubmed/28892244
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708640
Tagiau: Ychwanegu Tag
Dim Tagiau, Byddwch y cyntaf i dagio'r cofnod hwn!

Eitemau Tebyg