Gold(III) Alkyne Complexes: Bonding and Reaction Pathways

The synthesis and characterization of hitherto hypothetical Au(III) π‐alkyne complexes is reported. Bonding and stability depend strongly on the trans effect and steric factors. Bonding characteristics shed light on the reasons for the very different stabilities between the classical alkyne complexe...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Rocchigiani, Luca, Fernandez‐Cestau, Julio, Agonigi, Gabriele, Chambrier, Isabelle, Budzelaar, Peter H. M., Bochmann, Manfred
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2017
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5698712/
https://ncbi.nlm.nih.gov/pubmed/28892244
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708640
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