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Reactivity of Gold Hydrides: O(2) Insertion into the Au–H Bond
[Image: see text] Dioxygen reacts with the gold(I) hydride (IPr)AuH under insertion to give the hydroperoxide (IPr)AuOOH, a long-postulated reaction in gold catalysis and the first demonstration of O(2) activation by Au–H in a well-defined system. Subsequent condensation gave the peroxide (IPr)Au–OO...
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| Publicado no: | Organometallics |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4482408/ https://ncbi.nlm.nih.gov/pubmed/26146435 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om501165z |
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