Reactivity of Gold Hydrides: O(2) Insertion into the Au–H Bond

[Image: see text] Dioxygen reacts with the gold(I) hydride (IPr)AuH under insertion to give the hydroperoxide (IPr)AuOOH, a long-postulated reaction in gold catalysis and the first demonstration of O(2) activation by Au–H in a well-defined system. Subsequent condensation gave the peroxide (IPr)Au–OO...

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Bibliografiske detaljer
Udgivet i:Organometallics
Main Authors: Roşca, Dragoş-Adrian, Fernandez-Cestau, Julio, Hughes, David L., Bochmann, Manfred
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2014
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4482408/
https://ncbi.nlm.nih.gov/pubmed/26146435
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om501165z
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