Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides

The reduction of U(VI) uranyl halides or amides with simple Ln(II) or U(III) salts forms highly symmetric, linear, oxo‐bridged trinuclear U(V)/Ln(III)/U(V), Ln(III)/U(IV)/Ln(III), and U(IV)/U(IV)/U(IV) complexes or linear Ln(III)/U(V) polymers depending on the stoichiometry and solvent. The reaction...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Arnold, Polly L., Cowie, Bradley E., Suvova, Markéta, Zegke, Markus, Magnani, Nicola, Colineau, Eric, Griveau, Jean‐Christophe, Caciuffo, Roberto, Love, Jason B.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5697649/
https://ncbi.nlm.nih.gov/pubmed/28686336
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705197
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