Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides

The reduction of U(VI) uranyl halides or amides with simple Ln(II) or U(III) salts forms highly symmetric, linear, oxo‐bridged trinuclear U(V)/Ln(III)/U(V), Ln(III)/U(IV)/Ln(III), and U(IV)/U(IV)/U(IV) complexes or linear Ln(III)/U(V) polymers depending on the stoichiometry and solvent. The reaction...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Arnold, Polly L., Cowie, Bradley E., Suvova, Markéta, Zegke, Markus, Magnani, Nicola, Colineau, Eric, Griveau, Jean‐Christophe, Caciuffo, Roberto, Love, Jason B.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2017
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5697649/
https://ncbi.nlm.nih.gov/pubmed/28686336
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705197
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