Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin

The uranyl(vi) complex UO(2)Cl(L) of the redox-active, acyclic diimino-dipyrrin anion, L(–) is reported and its reaction with inner- and outer-sphere reductants studied. Voltammetric, EPR-spectroscopic and X-ray crystallographic studies show that chemical reduction by the outer-sphere reagent CoCp(2...

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Publicado en:Chem Sci
Autores principales: Pankhurst, James R., Bell, Nicola L., Zegke, Markus, Platts, Lucy N., Lamfsus, Carlos Alvarez, Maron, Laurent, Natrajan, Louise S., Sproules, Stephen, Arnold, Polly L., Love, Jason B.
Formato: Artigo
Lenguaje:Inglês
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5304617/
https://ncbi.nlm.nih.gov/pubmed/28451154
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02912d
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