Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides

The reduction of U(VI) uranyl halides or amides with simple Ln(II) or U(III) salts forms highly symmetric, linear, oxo‐bridged trinuclear U(V)/Ln(III)/U(V), Ln(III)/U(IV)/Ln(III), and U(IV)/U(IV)/U(IV) complexes or linear Ln(III)/U(V) polymers depending on the stoichiometry and solvent. The reaction...

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Detalles Bibliográficos
Publicado en:Angew Chem Int Ed Engl
Autores principales: Arnold, Polly L., Cowie, Bradley E., Suvova, Markéta, Zegke, Markus, Magnani, Nicola, Colineau, Eric, Griveau, Jean‐Christophe, Caciuffo, Roberto, Love, Jason B.
Formato: Artigo
Lenguaje:Inglês
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5697649/
https://ncbi.nlm.nih.gov/pubmed/28686336
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201705197
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