Differential uranyl(v) oxo-group bonding between the uranium and metal cations from groups 1, 2, 4, and 12; a high energy resolution X-ray absorption, computational, and synthetic study

The uranyl(vi) ‘Pacman’ complex [(UO(2))(py)(H(2)L)] A (L = polypyrrolic Schiff-base macrocycle) is reduced by Cp(2)Ti(η(2)-Me(3)SiC[triple bond, length as m-dash]CSiMe(3)) and [Cp(2)TiCl](2) to oxo-titanated uranyl(v) complexes [(py)(Cp(2)Ti(III)OUO)(py)(H(2)L)] 1 and [(ClCp(2)Ti(IV)OUO)(py)(H(2)L)...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Zegke, Markus, Zhang, Xiaobin, Pidchenko, Ivan, Hlina, Johann A., Lord, Rianne M., Purkis, Jamie, Nichol, Gary S., Magnani, Nicola, Schreckenbach, Georg, Vitova, Tonya, Love, Jason B., Arnold, Polly L.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6993744/
https://ncbi.nlm.nih.gov/pubmed/32055343
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc05717f
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