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Enantio- and Diastereoselective Organocatalytic Conjugate Additions of Nitroalkanes to Enone Diesters

Enantio- and diastereoselective conjugate addition reactions between nitroethane or nitropropane and enone diesters are reported. A bifunctional triaryliminophosphorane catalyzed the addition reaction with consistently excellent stereoselectivities and yields across a wide range of substrates. By th...

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Publicat a:Org Lett
Autors principals: Horwitz, Matthew A., Fulton, Jennifer L., Johnson, Jeffrey S.
Format: Artigo
Idioma:Inglês
Publicat: 2017
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5669806/
https://ncbi.nlm.nih.gov/pubmed/29035548
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b02735
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