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Asymmetric Organocatalytic Sulfa-Michael Addition to Enone Diesters

An asymmetric sulfa-Michael addition of alkyl thiols to enone diesters is reported. The reaction is catalyzed by a bifunctional triaryliminophosphorane-thiourea organocatalyst and provides a range of α-sulfaketones in high yields and enantioselectivities. Leveraging the gem-diester functional handle...

詳細記述

保存先:
書誌詳細
出版年:J Org Chem
主要な著者: Fulton, Jennifer L., Horwitz, Matthew A., Bruske, Ericka L., Johnson, Jeffrey S.
フォーマット: Artigo
言語:Inglês
出版事項: 2018
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5856655/
https://ncbi.nlm.nih.gov/pubmed/29512387
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b00007
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