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Asymmetric Organocatalytic Sulfa-Michael Addition to Enone Diesters
An asymmetric sulfa-Michael addition of alkyl thiols to enone diesters is reported. The reaction is catalyzed by a bifunctional triaryliminophosphorane-thiourea organocatalyst and provides a range of α-sulfaketones in high yields and enantioselectivities. Leveraging the gem-diester functional handle...
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| 出版年: | J Org Chem |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5856655/ https://ncbi.nlm.nih.gov/pubmed/29512387 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b00007 |
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