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Enantio and Diastereoselective Addition of Phenylacetylene to Racemic α-chloroketones

In this report, we have presented the first diastereoselective addition of phenylacetylene to chiral racemic chloroketones. The addition is controlled by the reactivity of the chloroketones that allowed the stereoselective reaction to be performed at –20 °C. Chiral racemic chloroketones are used in...

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Publicado en:Molecules
Autores principales: Alesi, Silvia, Emer, Enrico, Capdevila, Montse Guiteras, Petruzziello, Diego, Gualandi, Andrea, Cozzi, Pier Giorgio
Formato: Artigo
Lenguaje:Inglês
Publicado: MDPI 2011
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6264675/
https://ncbi.nlm.nih.gov/pubmed/21701439
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules16065298
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