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Enantio and Diastereoselective Addition of Phenylacetylene to Racemic α-chloroketones

In this report, we have presented the first diastereoselective addition of phenylacetylene to chiral racemic chloroketones. The addition is controlled by the reactivity of the chloroketones that allowed the stereoselective reaction to be performed at –20 °C. Chiral racemic chloroketones are used in...

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Опубликовано в: :Molecules
Главные авторы: Alesi, Silvia, Emer, Enrico, Capdevila, Montse Guiteras, Petruzziello, Diego, Gualandi, Andrea, Cozzi, Pier Giorgio
Формат: Artigo
Язык:Inglês
Опубликовано: MDPI 2011
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC6264675/
https://ncbi.nlm.nih.gov/pubmed/21701439
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules16065298
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