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Enantio and Diastereoselective Addition of Phenylacetylene to Racemic α-chloroketones

In this report, we have presented the first diastereoselective addition of phenylacetylene to chiral racemic chloroketones. The addition is controlled by the reactivity of the chloroketones that allowed the stereoselective reaction to be performed at –20 °C. Chiral racemic chloroketones are used in...

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書目詳細資料
發表在:Molecules
Main Authors: Alesi, Silvia, Emer, Enrico, Capdevila, Montse Guiteras, Petruzziello, Diego, Gualandi, Andrea, Cozzi, Pier Giorgio
格式: Artigo
語言:Inglês
出版: MDPI 2011
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC6264675/
https://ncbi.nlm.nih.gov/pubmed/21701439
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules16065298
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