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Enantio‐ and Diastereoselective Suzuki–Miyaura Coupling with Racemic Bicycles
Herein, we describe a rhodium‐catalyzed enantio‐ and diastereoselective Suzuki–Miyaura cross‐coupling between racemic fused bicyclic allylic chlorides and boronic acids. The highly stereoselective transformation allows for the coupling of aryl, heteroaryl, and alkenyl boronic acids and gives access...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6771587/ https://ncbi.nlm.nih.gov/pubmed/31246358 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201906478 |
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