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Colibactin assembly line enzymes use S-adenosylmethionine to build a cyclopropane ring
Despite containing an α-amino acid, the versatile cofactor S-adenosylmethionine (SAM) is not a known building block for non-ribosomal peptide synthetase (NRPS) assembly lines. Here we report an unusual NRPS module from colibactin biosynthesis that uses SAM for amide bond formation and subsequent cyc...
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| Publicado no: | Nat Chem Biol |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5657534/ https://ncbi.nlm.nih.gov/pubmed/28805802 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchembio.2448 |
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