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The reactivity of an unusual amidase may explain colibactin’s DNA cross-linking activity

Certain commensal and pathogenic bacteria produce colibactin, a small molecule genotoxin that causes interstrand cross-links in host cell DNA. Though colibactin alkylates DNA, the molecular basis for cross-link formation is unclear. Here, we report that the colibactin biosynthetic enzyme ClbL is an...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Jiang, Yindi, Stornetta, Alessia, Villalta, Peter W., Wilson, Matthew R., Boudreau, Paul D., Zha, Li, Balbo, Silvia, Balskus, Emily P.
Format: Artigo
Jezik:Inglês
Izdano: 2019
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6728428/
https://ncbi.nlm.nih.gov/pubmed/31251062
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b02453
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