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Total Synthesis of (−)-Nahuoic Acid C(i) (B(ii))
A convergent total synthesis of (−)-nahuoic acid C(i)(B(ii)) (3), a novel cis-decalin polyketide has been achieved. Key synthetic transformations include Type II Anion Relay Chemistry (ARC) to construct the polyol chain, a Ti-catalyzed asymmetric Diels-Alder reaction to generate the cis-decalin skel...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2017
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5655813/ https://ncbi.nlm.nih.gov/pubmed/28933833 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b08683 |
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