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Total Synthesis of (−)-Aplaminal

[Image: see text] The total synthesis and assignment of absolute configuration of (−)-aplaminal (1), a cytotoxic metabolite from a sea hare possessing a triazobicyclo[3.2.1]octane skeleton, has been achieved. The synthesis entailed condensation of a monoprotected diamine (3) with dimethyl 2-oxomalon...

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Autors principals: Smith, Amos B., Liu, Zhuqing
Format: Artigo
Idioma:Inglês
Publicat: 2008
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2775134/
https://ncbi.nlm.nih.gov/pubmed/18754624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol801794f
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