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Total Synthesis of (−)-Calyciphylline N

The total synthesis of the architecturally complex Daphniphyllum alkaloid (−)-calyciphylline N has been achieved. Highlights of the synthesis include a Et(2)AlCl promoted, highly stereoselective susbtrate controlled intramolecular Diels-Alder reaction, a transannular enolate alkylation, an effective...

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Bibliografiske detaljer
Main Authors: Shvartsbart, Artem, Smith, Amos B.
Format: Artigo
Sprog:Inglês
Udgivet: 2013
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3908864/
https://ncbi.nlm.nih.gov/pubmed/24319987
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja411539w
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