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Total Synthesis of (−)-Calyciphylline N
The total synthesis of the architecturally complex Daphniphyllum alkaloid (−)-calyciphylline N has been achieved. Highlights of the synthesis include a Et(2)AlCl promoted, highly stereoselective susbtrate controlled intramolecular Diels-Alder reaction, a transannular enolate alkylation, an effective...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3908864/ https://ncbi.nlm.nih.gov/pubmed/24319987 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja411539w |
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