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Enantioselective Total Synthesis of (+)-Peniciketals A and B: Two Architecturally Complex Spiroketals
The enantioselective total syntheses of (+)-peniciketals A and B, two members of a family of architecturally complex spiroketals, has been achieved. Key synthetic transformations comprise Type I Anion Relay Chemistry (ARC) to construct the benzannulated [6,6]-spiroketal skeleton, a Negishi cross-cou...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8170783/ https://ncbi.nlm.nih.gov/pubmed/33496178 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c11424 |
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