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Detrifluoroacetylative Generation of Halogenated Enolates: Practical Access to Perhalogenated Ketones and Alkenes

[Image: see text] Sequential chlorination/fluorination of aromatic trifluoroacetylated ketones gives 1-aryl 2-chloro-2,4,4,4-tetrafluoro-butan-1,3-dione hydrates that are used for the synthesis of ketones and alkenes exhibiting a terminal bromochlorofluoromethyl group. The hydrates undergo detrifluo...

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Detalhes bibliográficos
Publicado no:Synthesis (Stuttg)
Main Authors: Balaraman, Kaluvu, Moskowitz, Max, Liu, Yang, Wolf, Christian
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5589145/
https://ncbi.nlm.nih.gov/pubmed/28890578
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0035-1561433
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