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Organocatalytic Decarboxylative Cyanomethylation of Difluoromethyl and Trifluoromethyl Ketones

An efficient organocatalytic method for the synthesis of difluoromethyl and trifluoromethyl substituted β-hydroxynitriles is introduced. The decarboxylative cyanomethylation of fluorinated ketones with readily available cyanoacetic acid gives a variety of tertiary alcohols in high yields and without...

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Publicat a:Adv Synth Catal
Autors principals: Balaraman, Kaluvu, Moskowitz, Max, Wolf, Christian
Format: Artigo
Idioma:Inglês
Publicat: 2018
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6615566/
https://ncbi.nlm.nih.gov/pubmed/31289455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201800876
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