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Stereoselective Synthesis of 3,3′-Bisindolines by Organocatalytic Michael Additions of Fluorooxindole Enolates to Isatylidene Malononitriles in Aqueous Solution

A highly diastereoselective organocatalytic reaction for the synthesis of fluorinated 3,3′-bisindolines exhibiting adjacent tetrasubstituted carbon stereocenters is described. A broad variety of heterochiral bisindolines was prepared in 91-99% yield using 3-fluorooxindoles and isatylidene malononitr...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Adv Synth Catal
Prif Awduron: Balaraman, Kaluvu, Ding, Ransheng, Wolf, Christian
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2017
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5939588/
https://ncbi.nlm.nih.gov/pubmed/29755308
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201701107
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