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Catalytic Enantioselective and Diastereoselective Allylic Alkylation with Fluoroenolates: Efficient Access to C3-Fluorinated and All-Carbon Quaternary Oxindoles

[Image: see text] Synthetically versatile 3,3-disubstituted fluorooxindoles exhibiting vicinal chirality centers were obtained in high yields and with excellent enantio-, diastereo- and regioselectivity by catalytic asymmetric fluoroenolate alkylation with allylic acetates. The reaction proceeds und...

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Vydáno v:Angew Chem Int Ed Engl
Hlavní autoři: Balaraman, Kaluvu, Wolf, Christian
Médium: Artigo
Jazyk:Inglês
Vydáno: 2016
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5289271/
https://ncbi.nlm.nih.gov/pubmed/28026079
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201608752
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