Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O(2) at Fe(ii) centers

Recent efforts to model the reactivity of iron oxygenases have led to the generation of nonheme Fe(III)(OOH) and Fe(IV)(O) intermediates from Fe(II) complexes and O(2) but using different cofactors. This diversity emphasizes the rich chemistry of nonheme Fe(ii) complexes with dioxygen. We report an...

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Bibliografiska uppgifter
I publikationen:Chem Sci
Huvudupphovsmän: Ségaud, Nathalie, Anxolabéhère-Mallart, Elodie, Sénéchal-David, Katell, Acosta-Rueda, Laura, Robert, Marc, Banse, Frédéric
Materialtyp: Artigo
Språk:Inglês
Publicerad: Royal Society of Chemistry 2015
Ämnen:
Chemistry
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5588783/
https://ncbi.nlm.nih.gov/pubmed/28936313
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc01891e
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