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Successive light-induced two electron transfers in a Ru–Fe supramolecular assembly: from Ru–Fe(ii)–OH(2) to Ru–Fe(iv)–oxo

In the present work we describe the synthesis and study of a Ru(II)–Fe(II) chromophore–catalyst assembly designed to perform the light-induced activation of an iron bound water molecule and subsequent photo-driven oxidation of a substrate. Using a series of spectroscopic techniques, we demonstrate t...

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Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Herrero, Christian, Quaranta, Annamaria, Sircoglou, Marie, Sénéchal-David, Katell, Baron, Aurélie, Marín, Irene Mustieles, Buron, Charlotte, Baltaze, Jean-Pierre, Leibl, Winfried, Aukauloo, Ally, Banse, Frédéric
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5488195/
https://ncbi.nlm.nih.gov/pubmed/28706653
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00024f
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