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Successive light-induced two electron transfers in a Ru–Fe supramolecular assembly: from Ru–Fe(ii)–OH(2) to Ru–Fe(iv)–oxo
In the present work we describe the synthesis and study of a Ru(II)–Fe(II) chromophore–catalyst assembly designed to perform the light-induced activation of an iron bound water molecule and subsequent photo-driven oxidation of a substrate. Using a series of spectroscopic techniques, we demonstrate t...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Royal Society of Chemistry
2015
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5488195/ https://ncbi.nlm.nih.gov/pubmed/28706653 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00024f |
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