טוען...
An unconventional mechanistic insight on SCF(3) formation from difluorocarbene and application to (18)F-labeled α-SCF(3) carbonyl compounds
We discovered trifluoromethylthiolation occurred through sulfuration of difluorocarbene with elemental sulfur for the first time, which overrides our putative and long-standing trifluoromethyl anion-based theory. This mechanistic elucidation not only allows the discovery of an unprecedented chemical...
שמור ב:
| הוצא לאור ב: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , , , , |
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2017
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5582945/ https://ncbi.nlm.nih.gov/pubmed/28194833 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611761 |
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