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Difluorocarbene-derived Trifluoromethylthiolation and [(18)F]Trifluoromethylthiolation of Aliphatic Electrophiles

The first trifluoromethylthiolation and [(18)F]trifluoromethylthiolation of alkyl electrophiles with in situ generated difluorocarbene in the presence of elemental sulfur and external (radioactive) fluoride ion is described. This transition metal-free approach is high yielding, compatible with varie...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Zheng, Jian, Wang, Lu, Lin, Jin-Hong, Xiao, Ji-Chang, Liang, Steven H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4692268/
https://ncbi.nlm.nih.gov/pubmed/26387796
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505446
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