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Oxidation of difluorocarbene and subsequent trifluoromethoxylation
As a versatile intermediate, difluorocarbene is an electron-deficient transient species, meaning that its oxidation would be challenging. Herein we show that the oxidation of difluorocarbene could occur smoothly to generate carbonyl fluoride. The oxidation process is confirmed by successful trifluor...
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| Udgivet i: | Nat Commun |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Nature Publishing Group UK
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6877537/ https://ncbi.nlm.nih.gov/pubmed/31767850 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-13359-z |
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