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Prediction of NHC-catalyzed chemoselective functionalizations of carbonyl compounds: a general mechanistic map
Generally, N-heterocyclic carbene (NHC) complexed with carbonyl compounds would transform into several important active intermediates, i.e., enolates, Breslow intermediates, or acylazolium intermediates, which act as either a nucleophile (Nu) or an electrophile (E) to react with the other E/Nu partn...
में बचाया:
| में प्रकाशित: | Chem Sci |
|---|---|
| मुख्य लेखकों: | , , , , , , , |
| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
The Royal Society of Chemistry
2020
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| विषय: | |
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8159411/ https://ncbi.nlm.nih.gov/pubmed/34123007 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01793k |
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