Sequential Enzymatic Conversion of α‐Angelica Lactone to γ‐Valerolactone through Hydride‐Independent C=C Bond Isomerization

A case of hydride‐independent reaction catalyzed by flavin‐dependent ene‐reductases from the Old Yellow Enzyme (OYE) family was identified. α‐Angelica lactone was isomerized to the conjugated β‐isomer in a nicotinamide‐free and hydride‐independent process. The catalytic cycle of C=C bond isomerizati...

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Bibliografische gegevens
Gepubliceerd in:ChemSusChem
Hoofdauteurs: Turrini, Nikolaus G., Eger, Elisabeth, Reiter, Tamara C., Faber, Kurt, Hall, Mélanie
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: John Wiley and Sons Inc. 2016
Onderwerpen:
Communications
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5574032/
https://ncbi.nlm.nih.gov/pubmed/27885835
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cssc.201601363
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