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Highly diastereoselective synthesis of tricyclic fused-pyrans by sequential hydride shift mediated double C(sp(3))–H bond functionalization
Described herein is the Brønsted acid-catalyzed double C(sp(3))–H bond functionalization of alkyl phenethyl ether derivatives. In this process, a [1,5]-[1,5]-hydride shift occurred successively to afford tricyclic fused pyran derivatives in excellent chemical yields with excellent diastereoselectivi...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6237131/ https://ncbi.nlm.nih.gov/pubmed/30542535 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc02103a |
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