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Nicotinamide-independent asymmetric bioreduction of C[bond, double bond]C-bonds via disproportionation of enones catalyzed by enoate reductases
The asymmetric bioreduction of activated C[bond, double bond]C-bonds catalyzed by a single flavoprotein was achieved via direct hydrogen transfer from a sacrificial 2-enone or 1,4-dione as hydrogen donor without requirement of a nicotinamide cofactor. Due to its simplicity, this system has clear adv...
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| Huvudupphovsmän: | , , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
Pergamon Press
2010
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3007678/ https://ncbi.nlm.nih.gov/pubmed/21270958 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.11.065 |
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